Sheet material comprising at least one watermark having a colored shade

ABSTRACT

The present invention relates to a sheet material comprising at least one first layer defining an outer surface of the sheet material and having at least one first color, at least one second layer comprising at least one watermark and having at least one second color, the first and second colors having at least different saturations and/or hue angles.

The present invention relates to a sheet material comprising at least one watermark.

It is known to use the watermarking technique to produce secure documents that must be protected against forgery attempts, these documents being, for example, bank notes means of payment, identification papers, travel documents, admission tickets for cultural or sporting events.

The presence of the watermark aims to make it impossible to copy the document by optical means such as photocopying, photography or digitization, because the medium of the copy does not contain the watermark from the original document.

Also known are watermarked papers used for decorative purposes, in particular for prestigious printing/writing papers, in particular papers for letterheads.

Watermarks are conventionally obtained by a molding or embossing operation of the wet sheet coming from the aqueous suspension of cellulose fibers during the manufacture of the paper. At this stage of manufacture, the cellulose fibers migrate easily in the aqueous suspension so that the aforementioned operation has the effect of increasing the concentration of fibers in the thickest areas of the sheet and reducing their concentration in the thinnest areas, the result obtained after drying the paper being that the latter comprises, when looked at in transmitted light, light areas low in fibers and dark areas with high fiber density.

The light areas are called low optical density areas, lower than that of vellum paper, the non-watermarked area of the paper and the dark areas are called high optical density areas, higher than that of vellum paper.

A need exists to improve further the security of sheet materials against forgery attempts.

A need also exists for watermarked papers, in particular in the field of fine papers or printing/writing papers, having a novel esthetic effect.

The subject of the invention is hence, according to one of its aspects, a sheet material, in particular for secure documents and/or value documents, comprising:

-   -   at least one first layer defining, preferably, an outer surface         of the sheet material and having at least one first color; and     -   at least one second layer comprising at least one watermark and         having at least one second color, the first and second colors         having at least different saturations C* and/or hue angles h.

At least one of the layers may incorporate a dyeing agent in its mass, chosen so as to give said layer a colored shade over part or all of the surface of said layer.

The second layer is preferably a fibrous layer, in particular cellulose-fiber-based.

The expression “sheet material” in the description and the claims may denote a fibrous sheet based on cellulose and/or synthetic and/or non-cellulose organic fibers and/or mineral fibers that are capable of containing, where appropriate, various fillers and various additives currently used in the papermaking industry. The sheet material may have a monolayer (single-ply) or a multilayer (multi-ply), composite or noncomposite, structure. A sheet material may, for example, have a relatively low thickness, in particular less than or equal to 1 mm, for example equal to around 100 μm, and be flexible.

All colors are possible. Preferably, however, neither of the two colors is the color white.

A “dyeing agent” is understood to be a soluble or insoluble agent able to color at least one of the layers in visible light.

A “colored shade” is understood to be a coloring appearing approximately continuous to the naked eye, in contrast to the coloring that may be obtained locally by incorporating fibers or flakes for example. A colored shade does not, however, exclude variations in hue. Conventionally, a colored shade is obtained by dispersing at least one dye and/or at least one pigment in the mass.

In an exemplary implementation of the invention, the sheet material may be conditioned on the reel, in particular before being cut to the desired format.

The various components of the color are defined in the CIE 1976 (L*, a*, b*) or CIELAB color space. The value a* corresponds to the position on the red-green axis and the value b* to the position on the blue-yellow axis. The saturation C* corresponds to the quantity (a*²+b*²)^(1/2). The hue angle h corresponds to the quantity arctan(a*/b*). L* denotes the lightness.

The sheet material according to the invention has the advantage of being more complicated to reproduce due to the presence of different color layers and of at least one watermark that appears, in transmitted light, with a colored shade, such a watermark being relatively difficult to copy.

Furthermore, the invention allows, where appropriate, improvement of the esthetics of the sheet material using the color of the watermark and that of the outer surfaces of the material.

In an exemplary implementation of the invention, at least one of the first and second layers has a lightness L* greater than 70, in particular 80 or 90.

The second layer may, if desired, exhibit a color having a saturation C* less than 50, in particular of 35 or 20, so as to appear in reflection with a shaded, low saturation color.

The second layer preferably incorporates in its mass at least one dyeing agent.

This dyeing agent may be of any type, being for example chosen from: a direct dye, an acid dye, a basic dye, an organic or mineral pigment, this list not being limiting.

The aforementioned first and second colors may be due to different dyeing agents and/or to different concentrations respectively present in the mass of the first and second layers.

The watermark may appear, in transmitted light, with a color having a hue angle corresponding approximately to that of the second layer observed in reflection.

The most opaque areas of the second layer, which may be fibrous, corresponding to the dark areas of the watermark may, where appropriate, exhibit a more sustained saturation that that of the lower opacity areas corresponding to the light areas of the watermark.

The contrast between the dark areas and the light areas of the watermark depend in particular on the nature and on the color of the dye(s) incorporated in the mass of the second layer.

For example, the watermark may appear with a more marked contrast in transmitted light when the second layer has a blue shade, in relation to a yellow shade for example.

In an exemplary implementation of the invention, the first layer is a fibrous layer attached to the second layer, which may also be fibrous.

The two layers may, for example, define two opposite outer surfaces of the sheet material.

The first layer may comprise at least one watermark.

The sheet material may appear, in transmitted light, with a color corresponding to the superposition of the respective colors of the two layers, while the respective watermarks of the two layers appear with different colors, in particular with different hue angles, due to the more marked contrast of the watermarks.

The invention may thus make attempted forgery of the sheet material relatively difficult due to the presence of a set of watermarks of different colors.

In particular, the invention may eliminate attempted reproduction of a sheet material using an operation of making a paper transparent using an appropriate substance as this operation of making the paper transparent is achromatic and therefore does not permit watermarks of different colors to be obtained.

The invention may in addition enable varied visual effects to be created.

The watermarks may, if desired, have colors reproducing those of a national flag, for example.

In an exemplary implementation of the invention, the watermarks of the two layers are arranged in such a way as to cooperate when the material is observed in transmitted light to form a composite pattern, the watermarks comprising for example, adjacent and or superposed portions. These watermarks may be arranged such that one is located relative to the other.

The composite pattern may be chosen from at least one of the following elements: an alphanumeric character, a symbol, a logo or a drawing.

The composite pattern comprises for example a portrait formed by a first watermark reproducing a face of a person and appearing in transmitted light with, for example, a pink shade and a second watermark reproducing the hair of the person and appearing in transmitted light with, for example, a yellow shade.

The invention thus enables a multicolor watermark to be reconstructed.

In another exemplary implementation of the invention, the first layer is without a watermark.

The sheet material may, where appropriate, comprise more than two, possibly fibrous, layers, for example three or four layers, at least some of which may comprise a watermark and have different colors.

The total thickness of the sheet material may be chosen such that its opacity does not appreciably affect the contrast of the watermark(s) observed in transmitted light.

The sheet material may, where appropriate, comprise a third coating layer comprising at least one dyeing agent, the three layers notably having different colors.

In an exemplary implementation of the invention, the first layer is a coating layer, deposited for example on the second layer.

A “coating layer” is conventionally understood to be a layer covering approximately the entire surface of the sheet material, thus constituting the outer surface of this material. A coating layer may be fibrous or nonfibrous.

The coating layer preferably comprises at least one dye.

The second layer may comprise at least one sizing agent in its mass.

The watermark of the second layer, especially when fibrous, observed in light transmitted through the coating layer, may appear with a color corresponding approximately to the color of this second layer.

The contrast, in transmitted light, between the color of the watermark and that of the outer surface, defined by the coating layer, may depend in particular on the choice of the color of the second layer and on that of the coating layer.

In an exemplary implementation of the invention, the sheet material comprises two coating layers defining two outer surfaces of the sheet material.

In an exemplary implementation of the invention, the coating layer penetrates the mass of the second layer, only over part of the thickness of this second layer.

This coating layer may, for example, be deposited by a surfacing treatment using a size press or by impregnation of the second layer.

The coating layer may, in a variant, be deposited by coating the second layer.

The coating layer may extend approximately only at the surface of the second layer, without penetrating the mass thereof, and in particular enable improvement of the printing result of the sheet material.

The coating layer may comprise, where appropriate, coating pigments.

This coating layer may be transparent or translucent and, for example, comprise at least one colloidal silica.

Reference may be made in particular to international application WO 02/20902, which describes an example of such a coating layer.

The coating layer may be a binder-based surface layer, advantageously arranged to give the structure printability characteristics and/or specific properties such as a variable optical effect.

The surface layer may be different from a lacquer. The surface layer may, in particular, be a composition comprising coating or surfacing pigments and at least one binder. The pigments may be natural or synthetic mineral pigments, in particular of kaolin and/or calcium carbonate and/or silica, possibly pyrogenic, and/or titanium dioxide, possibly pyrogenic, or even iridescent pigments, in particular of the mica-titanium type, or even plastic pigments, for example hollow plastic microspheres based on a styrene polymer, in particular on styrene acrylic. The mean diameter of the microspheres is in particular between 0.5 mm and 1.0 mm.

This layer may comprise at least one binder, in particular a starch or the synthetic binders usual in the papermaking industry, together with, optionally, any additives currently used by the person skilled in the art with the function of improving the rheological properties of the coating slip and of providing the layer with particular properties. The weight of the layer may be between 2 and 50 g/m² on one or each surface, that is, including a surfacing having a layer weight of between 2 and 10 g/m².

In a particular embodiment, the pigmented layer comprises 70 to 95% of pigments and 5 to 30% of binders, not counting additives.

According to a particular embodiment, the surface layer is at least translucent and comprises 30 to 50 parts by dry weight of pyrogenic silica and 50 to 70 parts by dry weight of an elastomer binder, in particular a polyurethane, the sum of the parts of these components being 100 in total, the weight of the deposited layer is between 1 and 15 g/m² per dry surface, preferably between 1 and 10 g/m² per surface, more preferably still between 2 and 7 g/m² per dry surface. The layer may comprise other dispersing agent additives, viscosity changing agents, plasticizers, bacteriostatic agents, fungicides for example. It is not excluded that it comprises other authentication or anti-forgery agents.

The sheet material may comprise two opposite outer surfaces having different colors in reflection under visible light, in particular different saturations and/or hue angles.

As a variant, the two outer surfaces have approximately identical colors in reflection under visible light.

The sheet material, in particular the second layer, may preferably comprise at least one watermark having a plurality of tones, for example shaded tones, for example an intaglio watermark.

The watermark may be a light watermark or a dark watermark.

In an exemplary implementation of the invention, the material may comprise at least one watermark with a multitone effect comprising a set of light areas arranged to form a half-tone image with light and dark tones. This half-tone image may comprise half-tone patterns formed, for example, by lines. The light areas of the watermark have a mass surface density strictly less than the vellum part of the remainder of the fibrous layer.

The sheet material may receive at least one subsequent printing.

The sheet material may comprise at least one authentication and/or identification element, chosen in particular from at least one of the following elements: an element for demonstrating forgery, in particular one that is visible and/or detectable using a specific detection device, an element with a variable, interferential and/or diffractive or iridescent optical effect, a liquid crystal element, a magnetic coating, markers detectable with X-ray fluorescence, biomarkers, a lacquer or an ink, luminescent, fluorescent or phosphorescent markers, photochromic, thermochromic, electroluminescent and/or piezochromic compounds and/or compounds that change color on contact with one or more predetermined products.

The sheet material may, where appropriate, comprise a wire or strip security element.

This security element may be at least partially incorporated in the sheet material, in particular between two fibrous layers, or be incorporated in the mass of one of the fibrous layers. This element may be incorporated totally in the material, or as a variant, partially incorporated so as to appear in windows on one surface of the material, at least one of the windows possibly passing through.

The sheet material may comprise a security element attached to an outer surface of the sheet material. This element comprises, for example, a patch or foil.

In an exemplary implementation of the invention, the sheet material is arranged so that it can appear with at least three different colors.

The production of at least one of the first and second layers may be based on cellulose and/or synthetic fibers.

Said at least one agent for dyeing the sheet material according to the invention may consist of a fluorescent agent that appears colored in visible light. In one embodiment, the fluorescent dyeing agent displays a colored effect under ultraviolet (UV) or infrared (IR) light.

A colored or non-colored fluorescent agent that is visible or invisible in visible light may also be added to the layer(s) containing said at least one agent for dyeing the sheet material according to the invention and/or to a different layer.

In a particular embodiment, the first and second layers incorporate first and second fluorescent agents respectively, the first and second fluorescent agents appearing different in visible light and/or in invisible light. At least one of the fluorescent agents, preferably both the fluorescent agents, is/are incorporated in the mass and provide a colored shade to the layer in which they are incorporated.

The subject of the invention is also a sheet material comprising:

-   -   at least one first layer; and     -   at least one second layer;         the first and second layers incorporating first and second         fluorescent agents respectively.

The first and/or second fluorescent agent(s) may appear colored in visible light and/or invisible light, in particular under UV or IR light. The first fluorescent agent may have a different color to that of the second fluorescent agent in visible light and/or non-visible light. In particular, the color of the first fluorescent agent in visible light may correspond to the color of the second fluorescent agent in non-visible light and the color of the first fluorescent agent in non-visible light correspond to the color of the second fluorescent agent in visible light. The transition from illumination in visible light to illumination in invisible light then inverts the colors.

The first and second fluorescent agents may cover first and second areas respectively, the first and second areas being arranged so as to form, in visible and/or invisible light, a coherent whole such as an image, a message, or a pattern.

The subject of the invention is also a sheet material comprising:

-   -   at least one first layer; and     -   at least one second layer;         at least one of the first and second layers incorporating at         least one dyeing agent, the other of said layers incorporating         at least one fluorescent agent that is invisible in visible         light. The dyeing agent may be a fluorescent agent displaying a         colored effect under UV or IR light. In one embodiment, one         layer does not comprise a fluorescent agent and the other layer         does not comprise a dyeing agent.

In all the embodiments employing a fluorescent agent, the fluorescent agent may be visible, for example under ultraviolet (UV) or infrared (IR) light. Like the dyeing agents, it may be particulate or dissolved, a dye or a pigment.

Generally speaking, the fluorescent agent(s) may cooperate with each other and/or with dyeing agents and/or with one or more watermarks incorporated in particular in the first and/or the second layer in order to define a coherent whole such as an image, a message or a pattern in visible or invisible light, by transparency or otherwise. The watermarks and/or the dyeing agents and/or the fluorescent agents may have different colors depending on the layers in which they are incorporated.

In all the embodiments employing a fluorescent agent, the sheet material may also comprise one or more of the features of the previously described material not containing a fluorescent agent, in particular one or more of the features relating to the nature of the dyeing agents, to the arrangement of areas comprising a dyeing agent, to the presence of watermarks, to the nature and the position of the layers, to the incorporation of dyeing agents in the mass so as to provide a colored shade etc. The first layer may in particular be a fibrous layer or a coating layer deposited by a surfacing treatment, in particular on the second layer, as previously described. It may be an outer layer. The second layer may also be a fibrous layer, in particular based on cellulose fibers.

The subject of the invention is also, according to another of its aspects, an article, in particular a secure document or a value document or a packaging device comprising a sheet material such as defined above.

The document may constitute one of the following elements: a bank note, an identification document, a passport page or cover, a visa, a coupon, a value document other than a bank note, for example a check, a protective label and/or authentication label, a traceability marker.

The packaging device comprises for example a piece of packaging.

The subject of the invention is also, according to another of its aspects, a method for manufacturing a sheet material comprising:

-   -   at least one first layer defining an outer surface of the sheet         material and having at least one first color; and     -   at least one second fibrous layer comprising at least one         watermark and having at least one second color, the first and         second colors having at least different saturations and/or hue         angles;         the method comprising the following step:     -   producing the watermark of the second fibrous layer in the wet         state, in particular using a papermaking machine, in particular         a cylinder vat machine or a Fourdrinier machine, the watermark         comprising in particular portions having a mass surface density         different to that of the rest of the sheet material.

The watermark may be produced conventionally on an embossed web of a cylinder mold or using a watermark roll (also called a dandy roll) on a fourdrinier.

According to another exemplary implementation of the invention, the watermark may be produced according to the method described in the patent application EP 1 122 360, using a set of masks present on the web of the papermaking machine, the watermark obtained comprising a set of clear areas arranged to form a half-tone image.

When the sheet material comprises first and second fibrous layers, the method may comprise the following steps:

-   -   forming the two fibrous layers on two cylinder molds of the         papermaking machine; and     -   joining the two fibrous layers while they are still wet.

In an exemplary implementation of the invention, the method comprises the following step:

-   -   depositing a first coating layer on the second fibrous layer, in         particular using a size press, an impregnation device or a         coating device used in the papermaking industry, for example of         the air knife or curtain coating type.

In order to avoid altering the color in the mass of the watermark it is advantageous to limit, or even prevent, penetration of the dyeing agent of the coating layer into the mass of the fibrous layer comprising said watermark.

This may be carried out, for example, by adding a sizing agent to the mass of said fibrous layer. The sizing agent may be based on alkyl ketene dimer, also known by the abbreviation AKD, or based on alkenyl succinic anhydride, also known by the abbreviation ASA, or on rosin for example.

The present invention will be able to be better understood on reading the following detailed description of nonlimiting exemplary implementations of the invention and on examining the appended drawings in which:

FIG. 1 schematically and partially represents a secure document and/or a value document according to the invention;

FIGS. 2 to 4 are schematic and partial cross-sectional views of the document of FIG. 1 according to different exemplary embodiments;

FIG. 5 schematically and partially represents a secure document and/or a value document according to another exemplary implementation of the invention, observed in transmitted light;

FIG. 6 schematically and partially represents the appearance of the two opposite surfaces of the document of FIG. 5, observed in reflection;

FIG. 7 schematically and partially represents a secure document and/or a value document according to another exemplary implementation of the invention;

FIGS. 8 to 11 schematically and partially represent, in cross section, a sheet material according to various exemplary implementations of the invention;

FIG. 12 schematically illustrates a step in the manufacture of a sheet material according to the invention; and

FIG. 13 is a schematic and partial detail view of a forming web from the papermaking machine illustrated in FIG. 12.

In the interests of clarity, in the drawings the relative proportions of various represented elements have not always been respected, as the views are schematic.

FIG. 1 shows a secure document and/or a value document 1 comprising a sheet material 2 and having printing 9.

In the example considered, the document 1 is a bank note.

As a variant, the document may be chosen from among: an identification document, a passport page, a visa, a coupon, a value document other than a bank note, for example a check, a protective label and/or authentication label, a traceability marker, a letterhead or paper for advertising purposes for example.

The sheet material 2 comprises first 3 and second 4 joined fibrous layers, each having at least one watermark 5 and 6 respectively.

The sheet material 2 may be manufactured in the following manner (see FIG. 12).

The first fibrous layer 3 may be formed on a first cylinder mold 11 of a papermaking machine 10 comprising two cylinder molds, the second fibrous layer 4 being formed on a second cylinder mold 12 of this machine 10.

Each cylinder mold 11, 12 comprises a vat 13 containing a suspension of fibers 14, for example cellulose fibers, in which a rotating web cylinder 15 defining a surface 16 in contact with which the corresponding fibrous layer 3, 4 is continuously formed.

The two fibrous layers 3 and 4 are joined while they are still wet by passing between one cylinder 15 and another rotating cylinder 17.

In order to form one or more watermarks on the fibrous layers 3 and 4, each rotating web cylinder 15 comprises one or more embossings 18 comprising recessed and/or projecting areas, as illustrated in FIG. 13.

For example, the rotating web cylinder 15 of the first cylinder mold 11 may comprise recessed areas so as to form a dark watermark 5 on the fibrous layer 3, the dark areas of the watermark 5 resulting from an accumulation of fibers in the recessed areas of the cylinder 15 during the formation of the layer 3.

The cylinder 15 of the second cylinder mold 12 may comprise raised areas so as to form a light watermark 6 on the fibrous layer 4, the light areas of the watermark 6 resulting from a lower fiber density.

The layers 3 and 4 may be joined in such a way that the watermark 6 of the layer 4 is turned in an opposite direction to the layer 3, as illustrated in FIG. 2.

As a variant, as illustrated in FIG. 3, the layers 3 and 4 may be joined in such a way that the watermark 6 is directed towards the layer 3.

The rotating web cylinders 15 of the cylinder molds 11 and 12 may be arranged in such a way that the watermarks 5 and 6 of the layers 3 and 4 respectively are dark watermarks, as illustrated in FIG. 4.

In another exemplary implementation of the invention, at least one of the layers 3 and 4 comprises an intaglio or multitone-effect watermark.

The watermarks 5 and 6 may in particular be intaglio watermarks having shaded tones.

In another exemplary implementation of the invention, at least one of the watermarks 5 and 6 comprises a set of light areas arranged to form a half-tone image with a multitone effect.

Such a watermark may be obtained by a method described, for example, in the patent application EP 1 122 360.

In the example being considered, the suspension 14 of fibers from the cylinder mold 11, or the cylinder mold 12 respectively, contains a dyeing agent chosen so as to give the fibrous layer 3, or the fibrous layer 4 respectively, a colored shade.

The dyeing agent may be of any type, being for example chosen from: a direct dye, an acid dye, a basic dye, an organic or mineral pigment, this list not being limiting.

The dyeing agent may be chosen in such a way that the fibrous layers 3 and 4 respectively have first and second colors with at least different saturations C* and/or hue angles h.

The first and second layers 3 and 4 may, for example, have a lightness L* greater than 70, in particular 80 or 90.

The fibrous layers 3 and 4 may have a color with a saturation less than 50, in particular 35 or 20, so as to appear, in reflection in visible light, with a shaded, low saturation color.

The sheet material 2 may thus appear, in transmitted light, with a color corresponding to the superposition of the respective colors of the two fibrous layers 3 and 4, while the respective watermarks 5 and 6 appear with different colors, in particular with different hue angles, due to the more marked contrast of the watermarks, as illustrated in FIG. 1.

Each watermark 5, 6 may define a pattern chosen from one of the following elements: an alphanumeric character, a symbol, a logo or a drawing.

The watermarks 5, 6 may be arranged so as to cooperate when the sheet material 2 is observed in transmitted light to form a composite pattern 20, as illustrated in FIG. 5.

The composite pattern 20 comprises, for example, a portrait formed by the first watermark 5 reproducing a face of a person and appearing in transmitted light with, for example, a pink shade and the second watermark 6 reproducing the hair of the person and appearing in transmitted light with, for example, a yellow shade.

The invention thus allows new optical effects to be created, and in particular a watermark with a multicolored appearance to be created.

When observed in reflection under visible light the opposite surfaces 21 and 22 of the sheet material 2 appear with different colors, in particular with different saturations and/or hue angles, as illustrated in FIG. 6.

Examples of embodiments of the sheet material 2 are given below.

EXAMPLE 1

The sheet material 2 is obtained by forming a two-ply paper comprising two plies (or fibrous layers) 3 and 4 joined at the wet end, each of the fibrous layers having a basis weight of 60 g/m².

The layer 3 has a blue shade through addition into the fibrous mass of a blue dye marketed under the reference Fexonyl B2G LA at 0.0125 commercial parts per 100 parts of cellulose. This layer 3 comprises a watermark representing a first portrait.

The layer 4 has a pink shade through addition into the fibrous mass of a red dye marketed under the reference Cartasol EBE at 0.05 commercial parts per 100 parts of cellulose. This layer 4 comprises a watermark representing a second portrait.

In reflected light, the sheet material appears two-colored, shaded pink on one surface and shaded blue on the other surface.

In transmitted light, the shade of the vellum area is “old rose” while the watermarks retain the basic shade of their respective fibrous layer. Thus a first blue portrait and a second pink portrait are observed.

Measurements in the CIELAB space were carried out under a D65/10° illuminant and are reproduced in the table below.

Measurement L* a* b* C* Blue shaded 93.5 −1.86 −2.61 3.2 surface Pink shaded 93.3 3.3 −1.98 3.84 surface

EXAMPLE 2

The sheet material 2 is obtained by forming a two-ply paper comprising two plies, or fibrous layers, 3 and 4 joined at the wet end, each of the fibrous layers having a basis weight of 50 g/m².

The layer 3 has a blue shade through addition into the fibrous mass of a blue dye marketed under the reference Cartaren FBLA at 0.2 commercial parts per 100 parts of cellulose. This layer 3 comprises a watermark representing a first portrait.

The layer 4 has a yellow shade through addition into the fibrous mass of a yellow dye marketed under the reference NCG LA at 0.25 commercial parts per 100 parts of cellulose. This layer 4 comprises a watermark representing a second portrait.

In reflected light, the sheet material appears two-colored, shaded blue on one surface and shaded yellow on the other surface.

In transmitted light, the shade of the vellum area is blue-green while the watermarks retain the basic shade of their respective fibrous layer. Thus a first blue portrait and a second yellow portrait are observed.

Measurements in the CIELAB space were carried out under a D65/10° illuminant and are reproduced in the table below.

Measurement L* a* b* C* Blue shaded 85.79 −15.76 −9.49 18.39 surface Yellow shaded 90.36 −9.47 6.31 11.38 surface

EXAMPLE 3

The sheet material 2 is obtained by forming a two-ply paper comprising two plies, or fibrous layers, 3 and 4 joined at the wet end, each of the fibrous layers having a basis weight of 50 g/m².

The layer 3 has a blue shade through addition into the fibrous mass of a blue dye marketed under the reference Cartaren FBLA at 0.12 commercial parts per 100 parts of cellulose. This layer 3 comprises a watermark representing a first portrait.

The layer 4 has a pink shade through addition into the fibrous mass of a red dye marketed under the reference Cartasol EBE at 0.2 commercial parts per 100 parts of cellulose. This layer 4 comprises a watermark representing a second portrait.

In reflected light, the sheet material appears two-colored, shaded blue on one surface and shaded pink on the other surface.

In transmitted light, the shade of the vellum area is “old rose” while the watermarks retain the basic shade of their respective fibrous layer. Thus a first blue portrait and a second pink portrait are observed.

Measurements in the CIELAB space were carried out under a D65/10° illuminant and are reproduced in the table below.

Location measurement L* a* b* C* Blue shaded 88.03 −7.58 −7.70 10.8 surface Pink shaded 87.92 5.88 −5.15 7.81 surface

The sheet material 2 may comprise a fibrous layer 3 or 4 without a watermark.

For example, the fibrous layer 3 alone includes a watermark 5, as illustrated in FIG. 8, so that the sheet material 2 causes a monochrome watermark to appear in transmitted light, as illustrated in FIG. 7.

In the examples that have just been described, the sheet material 2 comprises two joined fibrous layers.

It remains within the scope of the present invention if the sheet material comprises a single fibrous layer with a watermark and a shaded layer deposited on said fibrous layer.

FIG. 9 represents, in cross section, a sheet material 30 comprising a single fibrous layer 31 including a watermark, which is not shown, and a coating layer 32 deposited onto the fibrous layer 31, for example using a size press or an impregnation device.

The coating layer 32 comprises a dye so that the surface of the sheet material 30 defined by the coating layer 32 appears, in reflection, with a color different to that of the fibrous layer 31.

In the example being considered, this fibrous layer 31 comprises a dyeing agent incorporated in its mass and the watermark produced on this layer 31 appears in transmitted light with a colored shade corresponding approximately to the color of this layer 31.

FIG. 10 represents a sheet material 35 comprising two joined fibrous layers 3 and 4, each comprising a watermark, as described with reference to FIGS. 2 to 4.

Two coating layers 32 are deposited on the outer surfaces of the fibrous layers 3 and 4.

An example of the material 35 is given below.

EXAMPLE 4

The two-ply paper from Example 1 is used.

This paper receives a yellow coating layer on its opposite surfaces through surface treatment by a size press, the yellow dye being that marketed under the reference NCG LA at 0.5% as a commercial dose. This dose corresponds roughly to a rate of transfer of yellow dye to the paper of around 0.25 commercial parts per 100 parts of paper.

Measurement L* a* b* Saturation Yellow shaded 90.97 −10.28 28.59 30.38 surface

The sheet material 35 has a yellow shade in reflection, and a blue first portrait and a pink second portrait in transmitted light.

FIG. 11 represents a sheet material 36 comprising a fibrous layer 31 colored in the mass and having a watermark and two coating layers 32, deposited on the opposite surfaces of the fibrous layers 31.

An example of the sheet material 36 is given below.

EXAMPLE 5

The sheet material 30 comprises a single-ply paper with a basis weight of 85 g/m².

The paper or fibrous layer 31 has a blue shade through addition into the fibrous mass of a blue dye marketed under the reference Fexonyl B2G LA at 0.01 commercial parts per 100 parts of cellulose. This layer 31 comprises a watermark showing a portrait.

The surface of the wet fibrous layer is treated by a size press to deposit a yellow dye marketed under the reference NCG LA at 0.5% as a commercial dose. This dose corresponds roughly to a rate of transfer of yellow dye to the paper of around 0.25 commercial parts per 100 parts of paper.

Measurement L* a* b* C* Blue shade 94.9 −5.34 −2.31 5.81 vellum (before yellow coating) Vellum (after 92.05 −13.95 33.8 36.56 yellow coating)

Of course, the invention is not limited to the exemplary implementations that have just been described.

It is possible to produce, for example, a sheet material with at least three fibrous layers with relatively low thicknesses so as not to reduce the contrast of the watermarks present on the fibrous layers unduly.

As a variant, it is possible, for example, to produce a sheet material with two fibrous layers, each with at least one watermark, and a third coating layer deposited on one of the two fibrous layers, for example using a size press. The three layers are preferably of different colors.

Each surface of the sheet material may, where appropriate, be of more than one color.

The expression “comprising a” should be understood as being synonymous with “comprising at least one”, unless specified to the contrary. 

1. A sheet material comprising: at least one first fibrous layer or coating layer deposited by a surfacing treatment having at least one first color; at least one second layer comprising at least one watermark and having at least one second color; at least one of the first and second layers incorporating at least one dyeing agent in its mass, chosen so as to give said layer a colored shade.
 2. The material according to claim 1, the second layer being a fibrous layer.
 3. The material according to claim 1, at least one of the first and second layers having a lightness greater than
 70. 4. The material according to claim 1, the second layer exhibiting a color having a saturation less than
 50. 5. The material according to claim 1, the first and/or the second layer incorporating in its mass at least one dyeing agent chosen from a direct dye, an acid dye, a basic dye, an organic or mineral pigment.
 6. The material according to claim 1, said dyeing agent being a fluorescent agent that appears colored in visible light.
 7. The material according to claim 1, said dyeing agent being a fluorescent agent that displays a colored effect under UV or IR light.
 8. The material according to claim 1, the first and second layers incorporating in their mass first and second fluorescent agents respectively, appearing different colors in visible and/or invisible light.
 9. The material according to claim 1, one of said layers incorporating said dyeing agent in its mass, the other of said layers incorporating a fluorescent agent that is invisible in visible light in its mass.
 10. The material according to claim 1, the two layers defining two opposite outer surfaces of the sheet material.
 11. The material according to claim 1, the first layer comprising at least one watermark.
 12. The material according to claim 11, the watermarks of the two layers being arranged in such a way as to cooperate when the material is observed in transmitted light to form a composite pattern.
 13. The material according to claim 1, comprising a third coating layer comprising at least one dyeing agent, the three layers notably having different colors.
 14. The material according to claim 1, the first layer comprising cellulose fibers.
 15. The material according to claim 1, the first layer being a coating layer.
 16. The material according to claim 15, the coating layer comprising at least one dyeing agent.
 17. The material according to claim 1, the mass of the second layer comprising at least one sizing agent.
 18. The material according to claim 15, comprising two coating layers defining two opposite outer surfaces of the sheet material.
 19. The material according to claim 1, the second fibrous layer having a blue shade.
 20. The material according to claim 1, comprising two opposite outer surfaces having different colors in reflection.
 21. The material according to claim 1, comprising at least one watermarks having shaded tones.
 22. The material according to claim 1, comprising at least one watermark with a multitone effect comprising a series of light areas arranged to form a half-tone image.
 23. The material according to claim 1, the first layer defining an outer surface of the sheet material.
 24. The material according to claim 1, neither of the two layers being white.
 25. The material according to claim 1, the first and second colors having at least different saturations and/or hue angles.
 26. A sheet material comprising: at least one first layer comprising at least one watermark and defining an outer surface of the sheet material and having at least one first color; and at least one second layer comprising at least one watermark and having at least one second color, the first and second colors having at least different saturations and/or hue angles.
 27. A sheet material comprising: at least one first layer defining an outer surface of the sheet material and having at least one first color; at least one second layer comprising at least one watermark and having at least one second color, the first and second colors having at least different saturations and/or hue angles; at least one of the first and second layers incorporating a dyeing agent in its mass, chosen so as to give said layer a colored shade, the first layer having been deposited on the second layer while the two layers were still wet, by a surfacing treatment, by impregnation of the second layer; or by coating onto the second layer.
 28. An article comprising a sheet material according to claim
 1. 29. A method for manufacturing by papermaking means a sheet material according to claim 1 comprising the following step: producing the watermark of the second fibrous layer in the wet state, the watermark comprising parts having a surface mass different to that of the remainder of the sheet material.
 30. The method according to claim 29, comprising the following step: depositing a coating layer on the second fibrous layer.
 31. A sheet material comprising: at least one first layer; and at least one second layer; the first and second layers incorporating first and second fluorescent agents respectively.
 32. The sheet material according to claim 31, the first and/or second fluorescent agent(s) appearing colored in visible light and/or invisible light.
 33. The sheet material according to claim 31, the first fluorescent agent having a different color to that of the second fluorescent agent in visible and/or non-visible light.
 34. The sheet material according to claim 33, the color of the first fluorescent agent in visible light corresponding to the color of the second fluorescent agent in non-visible light and the color of the first fluorescent agent in non-visible light corresponding to the color of the second fluorescent agent in visible light.
 35. The sheet material according to claim 31, the first and second fluorescent agents covering first and second areas respectively, the first and second areas being arranged so as to form, in visible and/or invisible light, a coherent whole such as an image, a message, or a pattern.
 36. The sheet material according to claim 31, the first layer and/or the second layer comprising at least one watermark.
 37. The sheet material according to claim 36, said at least one watermark of the first layer and said at least one watermark of the second layer being arranged so as to form, by transparency, a coherent whole such as an image, a message, or a pattern.
 38. The sheet material according to claim 31, the first layer being a fibrous layer or a coating layer deposited by a surfacing treatment.
 39. A sheet material comprising: at least one first layer; and at least one second layer; the first and second layers incorporating at least one dyeing agent and at least one fluorescent agent that is invisible in visible light respectively.
 40. The sheet material according to claim 39, the first layer not incorporating a fluorescent agent.
 41. The sheet material according to claim 39, the dyeing agent being a fluorescent agent displaying a colored effect under UV or IR light.
 42. The material according to claim 2, the second layer being cellulose-fiber based.
 43. The material according to claim 3, the lightness being greater than 80 or
 90. 44. The material according to claim 4, the saturation being less than 35 or
 20. 45. The material according to claim 20, the two opposite outer surfaces having different saturation and/or hue angles.
 46. An article according to claim 28, being a secure document and/or a value document.
 47. The method according to claim 30, comprising the step of depositing a coating layer on the second fibrous layer using a size press, an impregnation device or a coating device used in the papermaking industry. 